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Books : Science : Chemistry : Physical & Theoretical : Physical Organic Chemistry
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SpartanModel replaces the plastic models used by past generations of organic chemistry students. This set of easy-to-use digital builders allows you to construct and manipulate 3-D molecules of any size or complexity.
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A classic textbook on mechanistic organic chemistry which is characterised particularly by its clarity, careful choice of examples and its general approach that is designed to lead to a ready understanding of the subject matter. This guidebook is aimed clearly at the needs of the student, with a thorough understanding of, and provision for, the potential conceptual difficulties he or she is likely to encounter.
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The emphasis of this book is on understanding the science of adhesion. Each section or chapter starts with a simple view of the subject area and then builds to a point at which more detail is available for the reader who is or wants to be a practitioner of the art and science of adhesion. Partial Contents: Mechanical Properties. Mechanical Tests of Adhesive Bond Performance. Basics of Intermolecular Forces and Surface Science. Basic Physical/Chemical Properties of Polymers. Relationship of Surface Science and Adhesion Science. Surface Preparation of Adherends for Adhesive Bonding. Chemistry and Physical Properties of Structural Adhesives.
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Designed to help students not only understand what has been done in the past, but also be able to develop new concepts and to see new relationships in the future, Carroll's text emphasizes the nature and limitations of knowledge in chemistry, the need to question the underlying bases of familiar concepts, and the usefulness of exploring the role of complementary models in the understanding and practice of organic chemistry.
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Every serious student of chemistry should try to develop a `feel' for the way molecules behave - for the way they are put together and especially for the rules of engagement which operate when molecules meet and react. This primer describes how stereoelectronic effects control this behavior. It is the only concise text on this topic at the undergraduate level. This is an important subject area and the comprehensive yet concise coverage in this book shows students how to build up a powerful but simple way of thinking about chemistry.
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This concise, authoritative, and up-to-date overview begins with a chapter in which modern terminology, definitions, and concepts of mechanisms and reactivity are introduced. The following chapters provide accounts of the mechanisms of four of the main classes of reactions of aliphatic compounds. Rather than simply presenting the mechanisms to the reader, these chapters begin with experimental evidence and then demonstrate how this leads to the mechanistic deductions. Problems at the end of each chapter and a short bibliography further enhance this volume.
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Extensively revised and updated, this second edition covers the basics of the subject and the mechanisms for a wide range of chemical reactions. The text emphasises the frontier orbital theory and the use of the Hückel molecular orbitals to account for chemical reactivity. This is fully supported by references to the necessary experimental evidence, extensive data and new research methods currently in use.
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A best-seller for the advanced physical organic chemistry course, the text uses organic mechanisms as the focal point for examining current research. The third edition also has an expanded discussion of electron transfer processes, including application of valence-bond configuration interaction and treatment of energy surface crossings in photochemical processes; improved treatment of chemically induced dynamic nuclear polarization (CIDNP); and a new appendix to Chapter 9 on electron spin resonance (ESR). The expanded discussion of molecular orbital theory includes an introduction to perturbation molecular orbital (PMO), and the material on nucleophilic substitution, photochemistry, and radicals has been extensively revised. End-of-chapter problems ranging in difficulty encourage further investigation of reactions. Appendices include transition state thermodynamics and isotrope effects.
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A practical introduction to orbital interaction theory and its applications in modern organic chemistry Orbital interaction theory is a conceptual construct that lies at the very heart of modern organic chemistry. Comprising a comprehensive set of principles for explaining chemical reactivity, orbital interaction theory originates in a rigorous theory of electronic structure that also provides the basis for the powerful computational models and techniques with which chemists seek to describe and exploit the structures and thermodynamic and kinetic stabilities of molecules. Orbital Interaction Theory of Organic Chemistry, Second Edition introduces students to the fascinating world of organic chemistry at the mechanistic level with a thoroughly self-contained, well-integrated exposition of orbital interaction theory and its applications in modern organic chemistry. Professor Rauk reviews the concepts of symmetry and orbital theory, and explains reactivity in common functional groups and reactive intermediates in terms of orbital interaction theory. Aided by numerous examples and worked problems, he guides readers through basic chemistry concepts, such as acid and base strength, nucleophilicity, electrophilicity, and thermal stability (in terms of orbital interactions), and describes various computational models for describing those interactions. Updated and expanded, this latest edition of
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Now in its 4th edition, this remains the ultimate reference for all questions regarding the properties and effects of solvents in organic chemistry. Retaining its proven concept, the handbook is completely updated and contains 15% more content, including new chapters on "Solvents and Green Chemistry", "Classification of Solvents by their Environmental Impact", and "Ionic Liquids".
From the contents:- Solute-Solvent Interactions
- Classification of Solvents
- Solvent Effects on the Position of Homogeneous Chemical Equilibria, on the Rate of Homogeneous Chemical Reactions and on Absorption Spectra of Organic Compounds
- Empirical Parameters of Solvent Polarity
Praise for previous editions:"Because reactions in chemical and biochemical laboratories are mostly performed in solution, this book is highly recommended to all chemists or biochemists involved in teaching or research." —A. T. Balaban, Journal of the American Chemical Society
"... it is well worth the time of every organic chemist to read this book and learn how solvents influence the myriad phenomena of organic chemistry. It is also a superb reference book ... with the largest bibliography on solvents and solvent effects. – ... every practicing organic chemist should either own a copy or have accesss to one." —R. Pagni, Journal of Chemical Education
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The theoretical basis of this book is developed ab ovo. This requires dealing with several problems arising in physical chemistry including the concept of entropy as a thermodynamic coordinate and its relation to probability. Thus Maxwell Boltzmann and Gibbs statistical thermodynamics, and quantum statistics are made considerable use of. A statistical mechanical derivation of the law of mass action for gases and solids is presented, and the problems arising in the application of the law of mass action to the liquid state are addressed. Molecular interactions and how to take them into account when deriving the law of mass action is discussed in some detail sketching a way alternativ to the use of activities. Finally, attention is drawn to the statistical mechanical background to Linear Free Energy Relationships (LFER's) and of Isokinetic Relationships (IKR's) and their connections with molecular interactions.
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Volume 26 of this work provides insights into the mechanisms of primary carbonization; reviews the graphitization of various carbon materials under applied pressures; discusses changes in the thermal-mechanical properties of carbon/carbon composites due to stress effects; describes factors that result in the acceleration of the graphitization process; addresses the carbonization and graphitization of aromatic polymide films, and the quality control and quality of graphite films; and more.
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This new edition follows its predecessors in showing how an understanding of mechanistic principles can usefully be applied to thinking about and planning the construction of organic compounds. It is designed for those who have had a brief introduction to organic chemistry. An elementary knowledge of the nomenclature and structures of organic compounds is assumed.
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By providing you with easily accessed information on the structure and physical/chemical properties of more than 13,000 environmentally important chemicals, this handbook simplifies the task of locating and analyzing common and obscure compounds alike.
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Advances in Physical Organic Chemistry provides the chemical community with authoritative and critical assessments of the many aspects of physical organic chemistry. The field is a fast developing one, with results and methodologies finding application from biology to solid state physics.
This latest volume deals comprehensively with investigations that can be traced back to the birth of the field but which are still proving critical to the understanding of the stability of organic molecules and the mechanisms for their reactions.
. Volume 37 of this hugely successful Advances in Physical Organic Chemistry series
. Comprehensive review articles covering various topics of interest within the physical organic chemistry field -
"Provides an overview of scientific and technological issues in environmental applications of carbon materials. Emphasizes the versatility of carbon materials in both gas- and liquid-phase environmental applications, including a discussion of emerging technologies. Highlights the power and potential opportunities afforded by NMR spectroscopy for understanding the interaction of carbon materials with adsorbed molecules."
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This 24th volume continues in the tradition of its predecessors, presenting authoritative, interdisciplinary coverage of contemporary topics in the field of carbon chemistry and physics. With contributions by leading international experts, this volume: describes pitch polymerization kinetics during mesophase formation and the constitution of coexisting phases in mesophase pitch during heat treatment; elucidates the mechanism of mesophase formation and pitch polymerization kinetics after mesophase formation; examines the importance of physical, solid-state, electro- and analytical chemistry in the study of carbon surfaces; discusses the theoretical background for the thermal conductivity of diamonds, single crystal diamonds and chemically-vapour-deposited diamond films; and explains the chemistry involved in the commercial fabrication and use of needle coke.
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Radicals play a major role as intermediates in many chemical reactions. They contribute to transformations in the atmosphere, living organisms, chemical synthesis, combustion and detonation amongst others. This comprehensive and conclusive book discusses all these aspects. N-centered Radicals deals with NOx and NCO, relatively stable radicals whose presence in the atmosphere influences the metabolism of living organisms. Also included are NHx, NCH and N3, important in radical studies, chemical synthesis, detonation and metabolism. Until now there has been no single volume bringing together all aspects of N-centered radical chemistry, from formation, to their chemistry in aqueous environments, biological systems and the atmosphere. N-centered Radicals is essential reading for researchers in organic, physical and environmental chemistry, biology and all others examining the effects of N-centered radicals.





















